Neutralization reactions

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Neutralization reactions is a double-replacement reaction. It has the general form:

HX + MOH Reactionarrow.gif MX + HOH

Neutralization reactions occur when an acid reacts with a base to produce a salt and water.

Neutralization.gif

This is a double replacement reaction because the ions in compounds HX and MOH switch partners. Therefore, neutralization reactions are double replacement reactions. The driving force behind neutralization reactions is the formation of water.

An acid reacts with a base to produce a salt and water.

Example

Let's examine the reaction of hydrochloric acid , HCl (aq) and sodium hydroxide, NaOH (aq) in details.

Hcl naoh.gif

Reaction of hydrochloric acid with sodium hydroxide produces sodium chloride and water.

In aqueous solution, HCl and NaOH exist as ions in solution. The salt, NaCl, that forms is soluble in water, therefore, also exists as ions in solution. Therefore, to describe the same reaction more precisely, we write the following reaction revealing the ions that exist in the solution.

Hcl naoh totalions.gif

Before reaction After reaction
Beakerofions before.gif Beakerofions.gif

Careful inspection of the beakers will reveal that the ions that have undergone reaction are the H+ and OH- ions. The Na+ ions and Cl- ions remain unchanged before and after the reaction. The Na+ ions and the Cl- ions are called spectator ions.

If we leave out the spectator ions, and write the equation involving those ions that participated in the reaction, we write the net ionic equation of neutralization.

Netionic.gif

Since H+ ions exist in solution as hydronium ions, H3O+ , we can write the net ionic equation in the following way.

Netionic h30.gif

External link

Neutralization reactions


Content suitability

BCIT courses: CHEM 0011