World of Chemistry

Chemistry 0010

The Periodic Table - Classification of the Elements

Topics you should learn:

  1. Periods and Groups

  2. Metals, Nonmetals and Semimetals

  3. General Trends of the Periodic Table

The Periodic Table
(i) Periods

The periodic table, as we know it today, is an array of the elements arranged in order of increasing atomic number. When the elements are arranged in order of increasing atomic number, the physical and chemical properties of the elements vary periodically at regular intervals. This relationship is known as the periodic law.

Use the button bar down below to view the periodic table as we know it today. Click on the symbols on the periodic table to find out the element's name, its atomic number and its atomic mass.


Check out this site to learn about the early periodic table.

Read:
  • 5.1 - The Periodic Law (page 105)

There are seven periods of elements in the periodic table.
Each period has a variation in physical and chemical properties. It starts with reactive metals at the left and ends with a nonreactive noble gas.

The number of the period gives the number of the outermost principal energy level that the valence electron(s) occupies. This is best illustrated by reviewing the arrangement of electrons in principal energy levels and the Bohr diagrams.

Need a review?
Take a look at a few examples:

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(ii) Groups

There are 18 vertical columns of elements in the periodic table. Each column is called a group of elements, or a family of elements. Elements in the same family tend to have similar properties.

There are two formats in labelling the groups on the periodic table. In some books (and on the Internet) you will find the "1-18" numbering sequence. In other books, you will find the more popular "1-8 A and B" group labelling system. In this course, we will use the latter system of labelling.

Learn the names associated with the Groups of Elements.

"A" elements
The Representative
Elements
Group IA Alkali metals
Group IIA Alkaline earth metals
Group VIIA Halogens
Group VIIIA Noble gases
"B" elements The Transition Elements


Check out these sites if you are interested in seeing some pictures of the elements.


Read:
  • 5.2 - The Periodic Table. Periods and Groups (page 106)
  • 5.3 - General Characteristics of the Groups (page 109)

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Metals, Nonmetals and Semimetals

Do you know where to locate:

Take a look at how the periodic table organizes these classes of elements.


(i) Metallic Bond

Metals have a tendency of forming cations. The bonding of atoms in metals is referred to as metallic bonds.

(ii) Ionic Bond

When metals on the left-hand-side of the periodic table react with nonmetallic elements on the right-hand-side of the periodic table to form compounds, these compounds are held together by ionic bonds.

(iii) Covalent Bond

The chemical bonds formed by sharing of electrons between non-metallic elements are referred to as covalent bonds .

Examples are:

These seven elements exist as diatomic molecules are the diatomic elements.


Read:
  • 6.4 - The Ionic Bond (page 124)
  • 6.5 - The Covalent Bond (page 128)

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General Trends of the Periodic Table
(i) Atomic Size

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(ii) Trends in Ionic Size

  1. Metal atoms tend to lose their valence electrons to form positive ions called cations.

    A metal ion has a radius that is approximately half that of the corresponding metal atom

  2. Nonmetal atoms tend to gain electrons to form negative anions.

    An anion is approximately twice that of the corresponding nonmetal atom.

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(iii) Isoelectronic species

For isoelectronic ions, the radius decreases as the positive nuclear charge increases.

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Trends in Melting Point and Boiling Point

The melting point and boiling point are measures of the attractive forces between atoms or molecules. Elements, such as metals, that have strong attractive forces have higher melting points and boiling points than nonmetals, which have very weak forces of attraction.

(i)The Halogens

The physical states of the halogens at room temperature varies from gas to liquid to solid as one moves down the group. As a result, the melting points and boiling points increase as one moves down the group.

(ii)The Alkali Metals

The alkali metals show a decrease in melting points and boiling points due to the weaker metallic bonds between atoms as their size increase down the group.

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Metallic Trend

The metallic elements are found on the left-hand-side of the periodic table.

The non-metallic elements are found on the right-hand-side of the periodic table.

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Rosamaría Fong, Instructor of Chemistry,
British Columbia Institute of Technology, Burnaby, B.C. Canada.

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Rosamaría Fong, Instructor of Chemistry
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