Shapes of Atomic Orbitals

The shapes that the atomic orbitals are related to the probabilities of finding the electron in a certain volume in space. Using the Cartesian coordinate system (x, y, and z axes) as a frame of reference, the nucleus of the atom is located at the origin. The diagrams below are called "Boundary Surface Diagrams". These diagrams show the volume of space which encloses 90% of the probability distribution of finding the electron within the orbitals' boundary surfaces.

The s orbital

There is one type of s orbital. It has the shape of a sphere.

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The p orbitals

There are three p orbitals. They have the shapes of a dumbbell.

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The d orbitals

There are five d orbitals. Four of them have the shapes of a cloverleaf. The fifth one resembles a p orbital with a donut around the middle.

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