Unit #5 COMPOUNDS

5.6 - Classification of Bond Type

Summary of Bond Types:

Most compounds contain polar covalent bonds. This type of bonding is actually somewhere between the nonpolar covalent bonds and ionic bonding.

The difference in electronegativities of atoms joined by a chemical bond allows us to classify the type of bond.

In general, let x be the difference in electronegativity between bonding atoms.

if then the bond is nonpolar covalent
if then the bond is polar covalent
if then the bond is ionic

For example,
Compound
x
Bond type
H2 2.1 - 2.1 = 0 nonpolar covalent
HCl 3.0 - 2.1 = 0.9 polar covalent
NaCl 3.0 - 0.9 = 2.1 ionic

NB: For HF, the difference in electronegativity is 1.9, but the H-F bond is classified as polar covalent. Keep in mind, the ranges of x given above serves as a guideline for classification of bond type. Other properties of the compound also determines the type of bond that is formed.


 


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